trans-Carbonylchloridobis[tris(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone trisolvate
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چکیده
منابع مشابه
trans-Carbonylchloridobis[tris(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone trisolvate
In the title compound, trans-[RhCl{P(C(10)H(7))(3)}(2)(CO)]·3C(3)H(6)O, where P(C(10)H(7))(3) is trinaphthyl-phosphine, the Rh-P bond lengths are 2.3360 (10) and 2.3258 (10) Å, while the Rh-Cl bond length is 2.3525 (11) Å. The coordination around the Rh atom shows a slightly distorted square-planar arrangement.
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The title compound, [RhCl(C(21)H(21)P)(2)(CO)]·C(3)H(6)O, was precipitated in trace yield from a reaction of RhCl(cod)(THP) with P(p-tol)(3) in a 1:1 acetone-d(6)/CD(3)OD solution under a hydrogen atmosphere [p-tol = p-tolyl, THP = tris-(hydroxy-meth-yl)phosphine, P(CH(2)OH)(3), and cod = 1,5-cyclo-octa-diene]. The complex displays a square-planar geometry around the Rh(I) atom. The complex mol...
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The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P-Rh-P angle of 175.27 (2)° and Rh-P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solve...
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The title rhodium Vaska-type complex, trans-[RhCl{P(C(6)H(11))(2)(C(6)H(4)-4-C(3)H(7))(2)}(2)(CO)], crystallizes with an accompanying acetone solvent mol-ecule. The metal atom shows a distorted square-planar coordination environment with selected important geometrical parameters of Rh-P = 2.3237 (6) and 2.3253 (6) Å, Rh-Cl = 2.3724 (6) Å, Rh-C = 1.802 (2) Å, P-Rh-P = 173.42 (2)° and Cl-Rh-C = 1...
متن کامل4,4′-Bipyridine–trans,trans-hexa-2,4-dienedioic acid (1/1)
The title cocrystal, C(10)H(8)N(2)·C(6)H(6)O(4), crystallizes with half-mol-ecules of 4,4'-bipyridine and trans,trans-hexa-2,4-dienedioic acid in the asymmetric unit, as each is located about a crystallographic inversion center. The bipyridine molecule is planar from symmetry. In the dicarboxylic acid molecule, the O-C-C-C torsion angle is -13.0 (2)°. In the crystal, O-H⋯N and C-H⋯O hydrogen bo...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811038505